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隧道建设(中英文) ›› 2011, Vol. 31 ›› Issue (S1): 176-180.

• 研究与探索 • 上一篇    下一篇

CO2储存环境对固井水泥性质影响之研究

李冠颖1,郭俊志1,谢其泰2,向性一1,王建力1   

  1. (1.成功大学资源工程系,台南;2.台湾大学地质科学系,台北)
  • 收稿日期:2011-06-13 出版日期:2011-08-05 发布日期:2011-11-04
  • 作者简介:李冠颖(1986—),台南市,2011年毕业于成功大学资源工程专业,硕士,助理工程师,现从事制造工程方面。
  • 基金资助:

    NSC98-3114-E008-003计划经费补助项目

A study on Mechanical and Microscopic Properties of API GCement with Ddditives Exposed to CO2-rich Environment

LEE Kuanyin1, KUO Chunchin1, HSIEH ChiTai2, HSIANG HsingI1, WANG CheinLee1   

  1. (1.Department of Resources Engineering, Cheng Kung University, Tainan; 2.Department of Geosciences, Taiwan University, Taipei)
  • Received:2011-06-13 Online:2011-08-05 Published:2011-11-04

摘要: CO2存入地下以地质封存方式进行减量是一项可行的工程手段。干燥情况下CO2基本没有危害。然而在进行地质封存时,气井通常在地下水层、盐水层等潮湿的环境下操作,CO2与水结合会形成碳酸,形成一个酸性的环境。实验室观测表明API G级油井水泥添加包括飞灰、膨润土、重晶石与硅粉在潮湿(100%)、饱和CO2条件(常压,70 ℃)环境养护条件下28 d,研究其力学性能、化学成分及微观结构之间的关系。实验项目包括抗压强度、微观结构分析、X射线衍射及EDS扫描电镜。观察其养护样品发现,API G级油井水泥添加飞灰的水泥呈现出最佳抗压强度及最深的碳化深度。而API G级油井水泥添加膨润土的水泥现出最低抗压强度及最浅的碳化深度。

关键词: CO2, API G级油井水泥

Abstract: Storing CO2 underground by geological reservoirs is one of the ways to reduce atmospheric greenhouse gases. In the dry situation, CO2 has not harmed. But, when doing the geological reservoirs, the situation was often on the aquifers or deep saline aquifers. CO2 combined with water will become the carbonic acid (H2CO3) that makes cement alkalinity and compressive lower. This paper attempts to study the mechanical properties, chemical compositions, and microscopic structures of API G cements with different additives in the saturatedCO2 condition (atmospheric pressure, 70 ℃). The additives under investigation include fly ash, bentonite, and barite with silicate. The evolution of the mechanical properties including compressive strength and microscopic structure analysis including XRD, EDS, and SEM, were recorded over a period of 28 days. The carbonized depths of the samples over time were also observed. This study finds that the API G cement with fly ash displays the best compressive strength with deepest penetrating depth of carbonization. The API G cement with bentonite with higher water content has the lowest compressive strength with shallowest penetrating depth of carbonization.

Key words: carbon dioxide (CO2), API G cements