ISSN 2096-4498

   CN 44-1745/U

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Influence of Metal Ion Complex on ζ  Potential in Shield Muck During Solidification

  • LIAO Yunyang ,
  • ZHANG Heng ,
  • LIAO Rupeng ,
  • LEI Mingcheng ,
  • DING Bosong ,
  • WANG You
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  • (1. Fifth Engineering Company CREGC, Chengdu 610031, Sichuan, China; 2. School of Civil Engineering, Central South University, Changsha 410075, Hunan, China)

Online published: 2024-12-20

Abstract

Conventional treatment of shield muck always causes adverse impact to ecological environment. Thus, to improve the resource utilization efficiency of shield muck, metal ion complex ZY-1 is used to strengthen the hydration reaction during the solidification process of shield muck. Through potential testing, the influence of ZY-1 on ζ potential across various particle surfaces is analyzed, and empirical parameter equations are provided. During the test, pure water is used and 1 mL of KCI electrolyte with a concentration of 0.01 mmol/L is added to make a test sample suspension to ensure a single variable environment. ZY-1 concentrations are set at 0, 20, 40, 60, 80, and 100 mmol/L, respectively. The results show the following: (1) Metal ion complex effectively reduces ζ potential on various particle surfaces, diminishing the outer electric layer thickness, narrowing particle spacing, and enhancing consolidation. (2) ZY-1 shows the most significant reduction in ζ potential on cement particle surfaces; at a concentration increase from 0 to 100 mmol/L, cement particle ζ potential decreases by 61.61%. (3) The sequence of metal ion complex impact on ζ potential across different particle surfaces is as follows: cement > shield muck > calcium carbonate > calcium sulfate.

Cite this article

LIAO Yunyang , ZHANG Heng , LIAO Rupeng , LEI Mingcheng , DING Bosong , WANG You . Influence of Metal Ion Complex on ζ  Potential in Shield Muck During Solidification[J]. Tunnel Construction, 2024 , 44(S2) : 144 -151 . DOI: 10.3973/j.issn.2096-4498.2024.S2.015

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